2-(1H-Benzotriazol-1-yl)-1-(4-bromobenzoyl)ethyl 2-chlorobenzoate
نویسندگان
چکیده
In the title compound, C(22)H(15)BrClN(3)O(3), the benzotriazole ring system makes dihedral angles of 2.43 (1) and 71.51 (1)° with the bromo-phenyl and chloro-phenyl rings, respectively; the angle between the latter two rings is 69.26 (1)°. In the crystal structure, mol-ecules are linked into chains by inter-molecular C-H⋯O hydrogen bonds. The crystal packing is further stabilized by π-π (with a centroid-centroid distance of 3.764 Å) and C-H⋯π inter-actions.
منابع مشابه
2-(1H-Benzotriazol-1-yl)-1-(4-ethylbenzoyl)ethyl 2-chlorobenzoate
In the crystal structure of the title compound, C(24)H(20)ClN(3)O(3), weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into chains extended along the a axis. The crystal studied was found to be an inversion twin.
متن کامل2-(1H-Benzotriazol-1-yl)-1-(3-bromobenzoyl)ethyl benzoate. Corrigendum
The chemical name of the title compound in the paper by Hu & Wang [Acta Cryst. (2009), E65, o392] is corrected and the structural diagram is updated.[This corrects the article DOI: 10.1107/S1600536809002608.].
متن کامل2-(1H-Benzotriazol-1-yl)-1-(4-bromobenzoyl)ethyl 4-methylbenzoate
In the mol-ecule of the title compound, C(23)H(18)BrN(3)O(3), the benzotriazole mean plane makes dihedral angles of 1.26 (1) and 87.39 (1)° with the tolyl and bromophenyl benzene rings, respectively, and the dihedral angle between the benzene rings is 87.27 (1)°. In the crystal structure, mol-ecules are linked into chains along the a axis by C-H⋯O inter-molecular hydrogen bonds. The structure i...
متن کامل2-(1H-Benzotriazol-1-yl)-1-(3-bromobenzoyl)ethyl benzoate
In the title compound, C(22)H(16)BrN(3)O(3), the dihedral angles between the benzotriazole mean plane and the benzene rings of 4.84 (1) and 89.50 (1)°. The dihedral angle between the two benzene rings is 84.77 (1)°. In the crystal structure, mol-ecules are linked into chains by inter-molecular C-H⋯O hydrogen bonds. The crystal packing is further stabilized by C-H⋯π inter-actions.
متن کاملEthyl 2-(1H-1,2,3-benzotriazol-1-yl)acetate
The title compound, C(10)H(11)N(3)O(2), was synthesized by the reaction of 1H-benzotriazole with ethyl 2-chloro-acetate in ethanol. The non-H atoms, excluding the benzotriazol-1-yl group, are almost coplanar (r.m.s. deviation of the non-H atoms = 0.0409 Å). The dihedral angle formed between this plane and the benzotriazole ring is 79.12 (5)° In the crystal, weak inter-molecular C-H⋯N and C-H⋯O ...
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